| MP 2001 Speakers |
Rheology as a Tool to Monitor
Gelation and to Charachterise Hydrogels
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Roskilde University, Department of Chemistry, DK-4000 Roskilde, Denmark. Tel: +45 46742477 Fax: +45 46743011 E-mail: hvidt@ruc.dk |
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| Biography
Søren
Hvidt is associate professor in Physical Chemistry at Roskilde
University. He holds
a Masters degree in Chemistry and Physics from University of
Copenhagen and a Ph.D. degree in Physical Chemistry from
University of Wisconsin-Madison.
He joined the staff in Roskilde after postdoctoral
positions in Madison and in Baltimore.
He was from 1985-1991 also a member of the Polymer group at
Risø National Laboratory. His
main research intererest is physical chemical studies of
biological and synthetic macromolecules in solutions and gels. He has primarily used rheological techniques to characterize
macromolecular structures and dynamics in a broad range of
systems. He has
taught several courses in applied and basic rheology, and he has
been a consultant on rheological projects for several companies. Søren Hvidt has presented his research at several national and international meetings. He was a co-founder of the Nordic Rheology Society (NRS), and has been the editor of its Annual Transactions. He was awarded the NRS Carl Klason award in 1999 and has served on the editorial board of Polymer Networks and Gels. He is a member of the Danish Chemical Society, Polymer Network Group, and the Society of Rheology.
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Abstract
Hydrogels
are gaining wide-spread applications in many industries and have
replaced less environmentally safe materials.
Hydrogels can be divided into physical and chemically
crosslinked gels, with important differences in solubility.
The characteristic feature of a hydrogel is its solid
nature despite high concentrations of water.
Gels are difficult to define precisely but the elastic
rather than viscous behavior is a characteristic.
The special viscosity and elasticity properties of
hydrogels are the main reason for their use in industry, and it is
therefore of importance to be able to monitor gelation during
production processes and to obtain optimal mechanical properties
of the final products. In this presentation, the use of rheology to charaterize gels and gelation will be discussed. Modern rheometers enable a range of experimental tests, and the type of information which can be obtained from different tests will be illustrated. It will be argued that small amplitude oscillations should be used to monitor gelation, and once the gel is formed other techniques can be used to characterize the gel. The yield stress is an important quantity for many applications of gels, and different ways to determine yield stresses will be illustrated. The rigidity of gels are primarily determined by the number of crosslinks in the gel. Many standard industrial tests are basically rheological tests, and for the SAG test which is used to grade pectins the relationship to fundamental rheological properties has been established.
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