| MP 2001 Speakers |
New Ethylene
Copolymers (ECPs) for Medical Applications
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DuPont de Nemours (Deutschland) GmbH, Du Pont-Str. 1, DE 61352, Bad Homburg v.d.H., Germany Tel: +49 6172872750 Fax: +49 6172872930 E-mail: heiko.e.schenck@deu.dupont.com |
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| Biography
Dr.
Heiko E. Schenck is a polymer chemist and is the segment leader
for healthcare applications and convenience at DuPont in Europe.
He holds a degree in Chemistry from the University of
Mainz/Germany. After
four years at IBM Heiko started 1989 with DuPont in Germany
working in sales and marketing. In the following six years at the
European Technical Center in Geneva the major focus was on
development and marketing of tie layer polymers. The assignment
included supervision of the technical team and responsibility for
rigid packaging application and extrusion. In this period 15 new
products for multilayer structures have been developed to
commercial level as well as new peel seal concepts based on
Polyolefines. In 1999 Heiko returned to Germany and took the
lead for medical and pharmaceutical packaging applications in
DuPont to which global account management and the lead for
convenience packaging applications was added in 2001. |
Abstract
Ethylencopolymers
are widely used in medical applications like forming webs,
colostomy bags, urine bags and tubing. In addition to the well
known and established copolymers we see more and more compounded
products and terpolymers, which are generated buy using a third
monomer in the polymer. The
comonomer level in the final polymer has a significant influence
on all the key properties of the product. Taking EVA (Ethylen-vinyl-acetat)
as an example increasing VA monomer level is reducing the
crystallinity and the melting point. As a consequence the seal
initiation temperature is lowered, the optical properties are
improved as well as the flexibility. The product is getting
tougher at the same time. Along with the higher monomer level the
polarity is increased which corresponds to high frequency
weldability and better adhesion to polar substrates. On the
processing side handling is becoming more critical due to
tackiness and thermal stability. The lower melting point may limit
the application temperature. A higher monomer level is weakening
the mechanical properties like stiffness. Acid
modified products like Acid-copolymers (ACRs) and Ionomers (SURLYNŽ)
improve hot tack, oil resistance and stress crack resistance with
increasing monomer level. In specific with Ionomers at strong
improvement of mechanical properties like toughness, stiffness and
puncture resistance goes along with a high monomer level and
increased neutralization. This special class of polymers (by
grade) is listed in the US drug master file (DMF) and is in line
with the pharmacopoeia. |